Hi,
If you check your first screen shot of settlement profile it has CTR, NWA & WBS. You need to click on new entries and add G/L from dropdown list and create and assign a secondary cost element (category 22) like you assigned 590000 (Category 21) now for CTR rule.
Contact your FICO consultant create a new secondary cost element category 22 and assign to GL account.
Regards
Bhaskar